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Perjalanan kustodi · dimulai di China

Southern Chinese clay to the dysprosium that lets a magnet run hot

Grades under a tenth of a percent, and almost the only heavy rare earths on the market.

1,000 tonnes of clay in the hillside
15 kg of dysprosium oxide
China → Germany China — Leaching the hill in place 1 China Germany — A motor that can get hot 2 Germany
Diberi nomor sesuai urutan perjalanan material. Klik suatu negara untuk membuka halamannya. Proyeksi ekuirektangular yang digambar dari sentroid negara — busur menunjukkan perbatasan mana yang dilintasi, bukan rute pelayaran yang sesungguhnya.

Apa yang sebenarnya bergerak

Heavy rare earths do not come from a conventional orebody. They come from weathered granite where the metal ions cling loosely to clay, and they are recovered by washing a salt solution through the hillside. The grade is tiny; the strategic weight is enormous.

Materialnya
Dysprosium
Varietasnya
Ion-adsorption clay, very low grade, unusually rich in heavy rare earths
Titik awal
China — Weathered granite hills in Jiangxi, Guangdong and Fujian
Mengapa rute ini dan bukan yang lain. In these clays the rare earths are adsorbed onto clay surfaces rather than locked in a crystal, so a simple salt solution displaces them. That is why a deposit at 0.05% can be economic when a hard-rock deposit at ten times the grade is not. No comparable heavy-rare-earth resource is in commercial production elsewhere.
Rantai yang paling sempit. This is the chokepoint. Dysprosium and terbium have essentially one source region and one separation industry.
Baca dua angka pada setiap langkah: apa yang masuk, dan apa yang keluar. Mengamati angka-angka itu menyusut adalah inti dari sini. Pada akhirnya Anda akan telah mengikuti seribu ton batuan hingga tersisa beberapa kilogram dari bahan yang sesungguhnya bekerja.

Langkah demi langkah, perbatasan demi perbatasan

01 Ekstraksi 800kg

China · Jiangxi and Guangdong dipegang oleh State-consolidated producers (Produsen negara)

Leaching the hill in place

Ammonium sulfate solution is injected into the weathered granite and collected downslope. The rare-earth ions swap places with ammonium on the clay and come out in solution. Nothing is blasted and, in modern practice, little is dug.

1,000 tonnesclay at ~0.05–0.2% REO 800 kgmixed rare earths in solution

Apa yang terjadi pada sisanya: Older, uncontrolled in-situ leaching left serious groundwater and slope-stability damage, which is much of why the industry was consolidated under state control.

Mengapa di sini: This deposit type needs a specific granite, a specific climate and millions of years. It is not a matter of looking harder elsewhere.

Leaching the hill in place
Mountain Pass Rare Earth Mine & Process… · CC BY-SA 4.0 via Wikimedia Commons
02 Pemrosesan 800kg

China · On site dipegang oleh Producers (Kimia)

Precipitating a mixed carbonate

The pregnant solution is precipitated into a mixed rare-earth carbonate — the intermediate everything downstream starts from.

800 kgmetal in solution 800 kgmixed carbonate

Mengapa di sini: Concentrating before transport, as always.

Precipitating a mixed carbonate
COOLING TOWERS AND SETTLING TANKS FOR R… · Public domain via Wikimedia Commons
03 Pemurnian 15kg

China · Ganzhou, Jiangxi dipegang oleh China Rare Earth Group and affiliates (Pemurni)

Separating the heavies

Solvent extraction, but far harder than for the light rare earths: dysprosium, terbium, holmium and erbium are even more alike than neodymium and praseodymium, so it takes more stages and more patience.

800 kgmixed carbonate 15 kgdysprosium oxide

Apa yang terjadi pada sisanya: Terbium, yttrium, gadolinium and the rest come out alongside. Yttrium is by far the largest fraction; dysprosium and terbium are the ones everyone actually wants.

Mengapa di sini: Heavy separation capacity is concentrated here to a degree unmatched by any other material in this atlas.

Rute yang tidak ditempuh The light rare earths in the same magnet Two routes, two continents, meeting at the magnet press.
Separating the heavies
Linde (previously AGA) air separation p… · CC BY-SA 3.0 via Wikimedia Commons
04 Komponen 15kg

China · Magnet plants dipegang oleh Magnet manufacturers (Produsen)

Diffused into a magnet's grain boundaries

Rather than alloying dysprosium throughout the magnet, it is painted on and diffused into the grain boundaries where it does the most good. The technique cut dysprosium use per magnet several-fold.

15 kgdysprosium oxide 15 kgdysprosium in finished magnets

Apa yang terjadi pada sisanya: This is substitution by engineering rather than by chemistry — same performance, a fraction of the scarce element.

Mengapa di sini: Grain-boundary diffusion is a process advantage held by a small number of manufacturers.

Diffused into a magnet's grain boundaries
Neodymium magnet - 19-11-2010.JPG · Public domain via Wikimedia Commons
05 Pasar akhir 15kg

Germany · Traction motors and turbines dipegang oleh Motor manufacturers (Produsen)

A motor that can get hot

Without dysprosium a neodymium magnet begins losing strength around 80 °C. A traction motor or a turbine nacelle routinely runs hotter than that. 15 kg is enough for several thousand car motors.

15 kgdysprosium 15 kgin service

Mengapa di sini: A few kilograms of a metal from a Chinese hillside is what lets an electric motor survive a summer traffic jam.

A motor that can get hot
Blaupunkt CR-4500 - drive unit - tape D… · CC BY-SA 4.0 via Wikimedia Commons

Ini adalah contoh terhitung. Contoh ini mengikuti kuantitas awal yang dinyatakan melalui hasil dan perolehan tipikal yang dipublikasikan, sehingga proporsinya dapat diperiksa; ini bukan catatan pengiriman tertentu. Fakta rute — negara mana saja, proses apa saja, dan mengapa material tersebut tidak dapat begitu saja ditangani di tempat lain — dikompilasi dari laporan publik.

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