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溯源记录 · 起始于 China

Southern Chinese clay to the dysprosium that lets a magnet run hot

Grades under a tenth of a percent, and almost the only heavy rare earths on the market.

1,000 tonnes of clay in the hillside
15 kg of dysprosium oxide
China → Germany China — Leaching the hill in place 1 China Germany — A motor that can get hot 2 Germany
按材料流转顺序编号。点击国家可打开其页面。 等距矩形投影,以各国质心为基点绘制——弧线表示跨越的边境,而非实际航行路线。

实际流转的物质

Heavy rare earths do not come from a conventional orebody. They come from weathered granite where the metal ions cling loosely to clay, and they are recovered by washing a salt solution through the hillside. The grade is tiny; the strategic weight is enormous.

材料
Dysprosium
品种
Ion-adsorption clay, very low grade, unusually rich in heavy rare earths
起点
China — Weathered granite hills in Jiangxi, Guangdong and Fujian
为何走这条路线而非其他路线。 In these clays the rare earths are adsorbed onto clay surfaces rather than locked in a crystal, so a simple salt solution displaces them. That is why a deposit at 0.05% can be economic when a hard-rock deposit at ten times the grade is not. No comparable heavy-rare-earth resource is in commercial production elsewhere.
最薄弱的环节。 This is the chokepoint. Dysprosium and terbium have essentially one source region and one separation industry.
阅读每个环节的两个数字:投入量与产出量。观察数字不断缩小,正是重点所在。到最后,你将追踪到一千吨矿石如何变为数千克真正发挥作用的物质。

逐步追踪,逐境跨越

01 开采 800kg

China · Jiangxi and Guangdong 持有方 State-consolidated producers (国有生产商)

Leaching the hill in place

Ammonium sulfate solution is injected into the weathered granite and collected downslope. The rare-earth ions swap places with ammonium on the clay and come out in solution. Nothing is blasted and, in modern practice, little is dug.

1,000 tonnesclay at ~0.05–0.2% REO 800 kgmixed rare earths in solution

其余部分的去向: Older, uncontrolled in-situ leaching left serious groundwater and slope-stability damage, which is much of why the industry was consolidated under state control.

为何选择此地: This deposit type needs a specific granite, a specific climate and millions of years. It is not a matter of looking harder elsewhere.

Leaching the hill in place
Mountain Pass Rare Earth Mine & Process… · CC BY-SA 4.0 via Wikimedia Commons
02 加工 800kg

China · On site 持有方 Producers (化学品)

Precipitating a mixed carbonate

The pregnant solution is precipitated into a mixed rare-earth carbonate — the intermediate everything downstream starts from.

800 kgmetal in solution 800 kgmixed carbonate

为何选择此地: Concentrating before transport, as always.

Precipitating a mixed carbonate
COOLING TOWERS AND SETTLING TANKS FOR R… · Public domain via Wikimedia Commons
03 精炼 15kg

China · Ganzhou, Jiangxi 持有方 China Rare Earth Group and affiliates (精炼商)

Separating the heavies

Solvent extraction, but far harder than for the light rare earths: dysprosium, terbium, holmium and erbium are even more alike than neodymium and praseodymium, so it takes more stages and more patience.

800 kgmixed carbonate 15 kgdysprosium oxide

其余部分的去向: Terbium, yttrium, gadolinium and the rest come out alongside. Yttrium is by far the largest fraction; dysprosium and terbium are the ones everyone actually wants.

为何选择此地: Heavy separation capacity is concentrated here to a degree unmatched by any other material in this atlas.

未走的那条路 The light rare earths in the same magnet Two routes, two continents, meeting at the magnet press.
Separating the heavies
Linde (previously AGA) air separation p… · CC BY-SA 3.0 via Wikimedia Commons
04 组件 15kg

China · Magnet plants 持有方 Magnet manufacturers (制造商)

Diffused into a magnet's grain boundaries

Rather than alloying dysprosium throughout the magnet, it is painted on and diffused into the grain boundaries where it does the most good. The technique cut dysprosium use per magnet several-fold.

15 kgdysprosium oxide 15 kgdysprosium in finished magnets

其余部分的去向: This is substitution by engineering rather than by chemistry — same performance, a fraction of the scarce element.

为何选择此地: Grain-boundary diffusion is a process advantage held by a small number of manufacturers.

Diffused into a magnet's grain boundaries
Neodymium magnet - 19-11-2010.JPG · Public domain via Wikimedia Commons
05 终端市场 15kg

Germany · Traction motors and turbines 持有方 Motor manufacturers (制造商)

A motor that can get hot

Without dysprosium a neodymium magnet begins losing strength around 80 °C. A traction motor or a turbine nacelle routinely runs hotter than that. 15 kg is enough for several thousand car motors.

15 kgdysprosium 15 kgin service

为何选择此地: A few kilograms of a metal from a Chinese hillside is what lets an electric motor survive a summer traffic jam.

A motor that can get hot
Blaupunkt CR-4500 - drive unit - tape D… · CC BY-SA 4.0 via Wikimedia Commons

本文为示例演算,以公开的典型产率和回收率对既定起始量逐步推算,各比例可供核验;这不是某批具体货物的记录。路线事实——途经哪些国家、经历哪些工序,以及为何该材料不能在其他地方简单处理——均来源于公开报道。

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